Shoulder chops are larger in size than rib and loin chops, and have a tougher muscle structure. This means that you will want to cook them slightly longer than a rib or loin chop, and at lower heat. They also benefit from a brine, a rub, or a marinade to help break down the tough muscle fibers. So, just like any other tough cut of meat, they require low, slow cooking, which makes them ideal for your slow cooker. You can’t quickly pan-fry or grill them.